Identifying Data 2014/15
Subject (*) Química Inorgánica 3 Code 610G01023
Study programme
Grao en Química
Descriptors Cycle Period Year Type Credits
Graduate 1st four-month period
Third Obligatoria 6
Language
Spanish
English
Prerequisites
Department Química Fundamental
Coordinador
Fernandez Lopez, Alberto A.
E-mail
alberto.fernandez@udc.es
Lecturers
Castro Garcia, Socorro
Fernandez Lopez, Alberto A.
Platas Iglesias, Carlos
E-mail
socorro.castro.garcia@udc.es
alberto.fernandez@udc.es
carlos.platas.iglesias@udc.es
Web
General description A Química Inorgánica 3 é unha materia obrigatoria do primeiro semestre do terceiro curso do Grao en Química. Dita materia pertence ao módulo "Química Inorgánica". Esta materia está dedicada ao estudo dos Compostos de Coordinación e dos Sólidos Inorgánicos, tanto desde o punto de vista estrutural e da ligazón, como do da reactividade dos primeiros. As competencias adquiridas nesta materia resultan indispensables para a materia Química Inorgánica 4, xunto coa cal forman a materia denominada "Ampliación de Química Inorgánica". Para o estudo da devandita materia é imprescindible ter ben asentadas as competencias das Químicas inorgánicas 1 e 2 do segundo curso e das Químicas Físicas 1 e 2, tamén de segundo curso. Á súa vez, as competencias de de a materia "Ampliación de Química Inorgánica" son necesarios para as materias Química Inorgánica Avanzada e Ciencias de Materiais de cuarto curso.


La Química Inorgánica 3 es una asignatura obligatoria del primer semestre del tercer curso del Grado en Química. Dicha asignatura pertenece al módulo "Química Inorgánica". Esta asignatura está dedicada al estudio de los Compuestos de Coordinación y de los Sólidos Inorgánicos, tanto desde el punto de vista estructural y del enlace, como del de la reactividad de los primeros. Las competencias adquiridas en esta asignatura resultan indispensables para la asignatura Química Inorgánica 4, junto con la cual forman la materia denominada "Ampliación de Química Inorgánica". Para el estudio de dicha materia es imprescindible tener bien asentadas las competencias de las Químicas inorgánicas 1 y 2 del segundo curso y de las Químicas Físicas 1 y 2, también de segundo curso. A su vez, las competencias de de la materia "Ampliación de Química Inorgánica" son necesarios para las asignaturas Química Inorgánica Avanzada y Ciencias de Materiales de cuarto curso.


“Inorganic Chemistry 3” is a compulsory course in the 1st semester of the 3rd year of the Degree in Chemistry. This subject belongs to the module "Inorganic Chemistry" and is dedicated to the study of Coordination Compounds and Inorganic Solids, both from the standpoint of the structures and bonding, as the reactivity of the former. To follow this course is essential to have well-established skills of “Inorganic Chemistry 1”, “Inorganic Chemistry 2”, “Physical Chemistry 1” and “Physical Chemistry 2” (all of the 2nd year). “Inorganic Chemistry 3” serves as the foundation for “Inorganic Chemistry 4” (3rd year, 2nd semester), “Advanced Inorganic Chemistry” and “Materials Science” (both of the 4th year).

Study programme competencies
Code Study programme competences
A1 Ability to use chemistry terminology, nomenclature, conventions and units
A4 Knowledge of main types of chemical reaction and characteristics of each
A5 Understanding of principles of thermodynamics and its applications in chemistry
A6 Knowledge of chemical elements and their compounds, synthesis, structure, properties and reactivity
A8 Knowledge of principles of quantum mechanics and atomic and molecular structure
A9 Knowledge of structural characteristics of chemical and stereochemical compounds, and basic methods of structural analysis and research
A10 Knowledge of chemical kinetics, catalysis and reaction mechanisms
A14 Ability to demonstrate knowledge and understanding of concepts, principles and theories in chemistry
A15 Ability to recognise and analyse new problems and develop solution strategies
A16 Ability to source, assess and apply technical bibliographical information and data relating to chemistry
A24 Ability to explain chemical processes and phenomena clearly and simply
A25 Ability to recognise and analyse link between chemistry and other disciplines, and presence of chemical processes in everyday life
B1 Learning to learn
B2 Effective problem solving
B3 Application of logical, critical, creative thinking
B4 Working independently on own initiative
B5 Teamwork and collaboration
B7 Effective workplace communication
C1 Ability to express oneself accurately in the official languages of Galicia (oral and in written)
C6 Ability to assess critically the knowledge, technology and information available for problem solving
C7 Acceptance as a professional and as a citizen of importance of lifelong learning
C8 Understanding role of research, innovation and technology in socio-economic and cultural development

Learning aims
Subject competencies (Learning outcomes) Study programme competences
To know the structure and the nature of chemical bonding in coordination compounds. A1
A6
A8
A9
A14
A15
A16
A24
A25
B1
B2
B3
B4
B5
B7
C1
C6
C7
C8
To know the thermodynamic aspects related to the stability of coordination compounds. A1
A5
A9
A14
A15
A16
B1
B2
B3
B4
B5
B7
C1
C6
C7
C8
To know the most important reaction mechanisms for coordination compounds. A1
A4
A9
A10
A14
A15
A16
B1
B2
B3
B4
B5
B7
C1
C6
C7
C8
To know the structure of inorganic solids. A1
A6
A9
A14
A15
A16
B1
B2
B3
B4
B5
B7
C1
C6
C7
C8
To know the microstructure of inorganic solids. A1
A6
A9
A14
A15
A16
A24
A25
B1
B2
B3
B4
B5
B7
C1
C6
C7
C8
To know the nature of chemical bonding in inorganic solids. A1
A5
A6
A8
A9
A14
A15
A16
A24
A25
B1
B2
B3
B4
B5
B7
C1
C6
C7
C8

Contents
Topic Sub-topic
1.- Introduction to Coordination Chemistry. Introduction
2.- Bonding in coordination compounds. - Valence bond theory.
- Crystal field theory.
- Molecular orbital theory.
3.- Thermodynamic stability of coordination compounds. - Introduction: stability/instability vs. inertia/lability.
- Stability constans.
- Factors that affect the stability of complexes.
4.- Reaction mechanisms of coordination compounds. - Ligand substitution reactions.
- Redox reactions.
5.- Introduction to Solid State Chemistry. Introduction.
6.- Ideal solids: Structural aspects and bonding. - Structures of solids.
- Bonding in solids: ionic model, band model.
7.- Real solids: defects in solids, examples of inorganic solids with relevant properties. - Defects in solids.
- Examples of solids with important properties.

Planning
Methodologies / tests Ordinary class hours Student’s personal work hours Total hours
Guest lecture / keynote speech 28 42 70
Workshop 7 21 28
Problem solving 7 24.5 31.5
Mixed objective/subjective test 4 15.5 19.5
 
Personalized attention 1 0 1
 
(*)The information in the planning table is for guidance only and does not take into account the heterogeneity of the students.

Methodologies
Methodologies Description
Guest lecture / keynote speech Lectures to introduce the most relevant issues related to the contents of the course, highlighting the most important aspects.
Workshop Practical activities to aid the understanding of the more difficult aspects of the course.
Problem solving Classes oriented to solve problems and exercises previously proposed to the students, so that they can work on them in advance.
Mixed objective/subjective test Final written exam that will take place at the end of the course with the aim to evaluate the global knowledge, understanding and skills acquired by each student.

Personalized attention
Methodologies
Workshop
Problem solving
Guest lecture / keynote speech
Description
Personalized attention will be held in small groups ("Talleres" and "Solución de problemas"), and also in individual interviews or tutorials proposed by the lecturer. Students can ask for additional tutoring sessions that will take place at the tutoring hours of the lecturer (the timetable will be indicated at the begining of the course).

Assessment
Methodologies Description Qualification
Workshop Aspects to be evaluated: the exercises and activities carried out in the working sessions, the participation on the discussions, the interaction with the other students.The following study competences will be assessed in workshops: A1, A8, A9, A16, B1, B2, B3, B4, B5, B7, C1.
WORKSHOPS and PROBLEM SOLVING will be assessed jointly.
0
Problem solving Aspects to be evaluated: The solution of the proposed problems and exercises in the seminars by the students, their participation in the discussions, and their interaction with the other students. The following study competences will be assessed in this activity: A1, A4, A5, A6, A8, A9, A10, A14, A15, A16, A24, A25, B1, B2, B3, B4, B5, B7, C1, C6, C7, C8.
WORKSHOPS and PROBLEM SOLVING will be assessed jointly.
30
Mixed objective/subjective test Final exam that may include short questions, multiple choice questions, and problems similar to those solved throughout the course. The following study competences will be assessed in the final exam: A1, A4, A5, A6, A8, A9, A10, A14, A15, A16, A24, A25, B2, B3, C1, C6. 70
 
Assessment comments

The final grade is the sum of:

- "Mixed test": up to 7 points

- "Problem solving" + "workshop": up to 3
points

To pass the course it is necessary to get a minimum of
5 points in that sum. Restriction: it is
necessary to obtain a minimum of 2.8 (relative to a maximum of 7) in the
“mixed test”. If this minimum of 2.8 is not reached, the final
grade will be the grade obtained in the “mixed test”

Since this is a continuous assessment model:

  1. the
    progression of the student throughout the semester can be graded with a maximum
    of 1 point that can be added to the final mark;

  2. the student will be graded if his/her participation in the course represents more than 20% of the
    global activities of the course;

  3. in accordance with the regulations (“Probas de Avaliación e Actas de Cualificación de Grao e
    Mestrado”), the "2nd opportunity" (July) is only a second chance for
    the final exam (“mixed test”). The
    grade on this 2nd opportunity of the “mixed test” will be added to those
    obtained during the course in “problem solving” + “workshops” . The percentages are the same as in the "1st opportunity".




  4. “Matricula de honor (MH)” is the highest grade,
    awarded to very outstanding students having passed the course in the “1st opportunity”. MH
    can be achieved in the "2nd opportunity" only if still available.

Only in very
exceptional circumstances (adequately justified) the student may be exempted
from the ongoing evaluation process. In that case, he must pass a special
examination to prove, without any doubt, the overall level of knowledge and
skills.


Sources of information
Basic (). .
(). .
M.T. Weller (1999). "Inorganic Materials Chemistry". Oxford University Press, Oxford
J. Rivas Gispert (2000). "Química de Coordinación". Ediciones Omega S.A.
P. W. Atkins, T. L. Overton, J. P. Rourke, M. T. Weller y F. A. Armstrong (2008). "Química Inorgánica de Shriver y Atkins" Versión en español de la 4ª edición de "Shriver and Atkins' Inorganic Chemistry". McGraw-Hill Interamericana
P. W. Atkins, T. L. Overton, J. P. Rourke, M. T. Weller and F. A. Armstrong. (2009). "Shriver and Atkins' Inorganic Chemistry" 5th ed.. W. H. Freeman and company, New York
A.R. West (1984). "Solid State Chemistry and its Aplications". John Wiley & Sons, New York
L. Smart & E. Moore (1992). "Solid State Chemistry: an Introduction". Chapman & Hall, London
J. Ribas Gispert (2008). Coordination Chemistry (versión en ingles de Química de Coordinación). Willey-VCH, Weinheim
L. Smart & E. Moore (1995). “Una introducción a la química del estado sólido”, versión española. Ed. Reverté, Barcelona

Complementary (). .
S. F. A. Kettle (1998). "Physical Inorganic Chemistry. A Coordination Chemistry Approach". Oxford University Press
A.F. Wells (1978). “Química inorgánica estructural” Versión española de la 4ª Ed.. Ed. Reverté, Barcelona
A.F. Wells (1984). “Structural Inorganic Chemistry” 5th Ed.. Oxford Univesity Press, London


Recommendations
Subjects that it is recommended to have taken before
Química Inorgánica 4/610G01024
Química Inorgánica Avanzada/610G01025
Ciencia de Materiais/610G01035

Subjects that are recommended to be taken simultaneously

Subjects that continue the syllabus
Química Física 1/610G01016
Química Física 2/610G01017
Química Inorgánica 1/610G01021
Química Inorgánica 2/610G01022

Other comments


(*)The teaching guide is the document in which the URV publishes the information about all its courses. It is a public document and cannot be modified. Only in exceptional cases can it be revised by the competent agent or duly revised so that it is in line with current legislation.