Teaching GuideTerm
Faculty of Science
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Mestrado Universitario en Investigación Química e Química Industrial (Plan 2017)
 Subjects
  Applied Coordination Chemistry
   Contents
Topic Sub-topic
Structural properties of coordination compounds. Characterization techniques Structural properties in coordination compounds.
Characterization techniques.
- Spectroscopic techniques
- Spectrometric techniques
- Diffraction techniques
- Techniques based on magnetic properties
- Other techniques
Activation of small molecules by coordination compounds Structure and bonding in dioxygen and dinitrogen complexes: bonding modes.
Synthesis of dioxygen and dinitrogen complexes.
Structural characterization of dioxygen and dinitrogen complexes: NMR and IR spectroscopy, mass spectrometry, single crystal X-ray diffraction.
Synthetic applications of dioxygen and dinitrogen complexes. Future perspectives.
Coordination compounds with applications in medicine: therapeutic and diagnose tools Coordination compounds with applications in medicine: therapeutic and diagnose tools
- Antitumor metalodrugs.
- Types of complexes according to the metal centre and the structure
- Therapeutic mechanism.
- Synthetic methods.
Application of metal complexes as radiopharmaceuticals.
- Properties and characteristics of the ligands and the radioisotope
- Diagnostic, (PET, SPEC) and therapeutic techniques.
Contrast agents in magnetic resonance imaging (MRI)
Proton relaxation agents T1 (Gd3+, Mn2+ y Fe3+) y T2. Parameters affecting the efficiency.
- Agents based on saturation transfer by chemical exchange (CEST).
- Agents based on other nuclei (, 31P).
- Hyperpolarization.
Coordination compounds in the design of new materials: coordination polymers and MOFs. Properties and applications. Types of systems arising from the metal-ligand association. Isolated and extensive associations (coordination polymers and MOFs) Main structural characteristics and characterization.
Synthetic strategies and general characterization techniques.
Properties and applications.
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