Identifying Data 2019/20
Subject (*) Structure and Reactivity of Organic Compounds Code 610509114
Study programme
Mestrado Universitario en Investigación Química e Química Industrial (Plan 2017)
Descriptors Cycle Period Year Type Credits
Official Master's Degree Yearly
First Optional 3
Language
Spanish
Galician
English
Teaching method Face-to-face
Prerequisites
Department Química
Coordinador
Ojea Cao, Vicente
E-mail
vicente.ojea@udc.es
Lecturers
Maestro Saavedra, Miguel Anxo
Ojea Cao, Vicente
E-mail
miguel.maestro@udc.es
vicente.ojea@udc.es
Web
General description Conocimento de forma completa e integrada dos principais mecanismos das reacciones orgánicas e dos principais métodos empleados na determinación do mecanismo de unha reacción en Química Orgánica. Comprensión dos efectos estereoelectrónicos na reactividad dos compuestos orgánicos e nos procesos de formación de ciclos e do efecto doa conformación doos compostos acíclicos e cíclicos na sua reactividade, y do Principio de Curtin-Hammett. Análise, de forma integrada, a xeración, a estructura e a evolución dos intermedios de reacción. Profundización nos principios e nas metodoloxías sintéticas basadas en reacciones pericíclicas.

Study programme competencies
Code Study programme competences
A1 Define concepts, principles, theories and specialized facts of different areas of chemistry.
A2 Suggest alternatives for solving complex chemical problems related to the different areas of chemistry.
A3 Innovate in the methods of synthesis and chemical analysis related to the different areas of chemistry
A6 Design processes involving the treatment or disposal of hazardous chemicals
A8 Analyze and use the data obtained independently in complex laboratory experiments and relating them with the chemical, physical or biological appropriate techniques, including the use of primary literature sources
B1 Possess knowledge and understanding to provide a basis or opportunity for originality in developing and / or applying ideas, often within a research context
B2 Students should apply their knowledge and ability to solve problems in new or unfamiliar environments within broader (or multidisciplinary) contexts related to their field of study.
B4 Students should be able to communicate their conclusions, and the knowledge and the reasons that support them to specialists and non-specialists in a clear and unambiguous manner
B5 Students must possess learning skills to allow them to continue studying in a way that will have to be largely self-directed or autonomous.
B7 Identify information from scientific literature by using appropriate channels and integrate such information to raise and contextualize a research topic
B10 Use of scientific terminology in English to explain the experimental results in the context of the chemical profession
B11 Apply correctly the new technologies to gather and organize the information to solve problems in the professional activity.
C1 CT1 - Elaborar, escribir e defender publicamente informes de carácter científico e técnico
C3 CT3 - Traballar con autonomía e eficiencia na práctica diaria da investigación ou da actividade profesional.
C4 CT4 - Apreciar o valor da calidade e mellora continua, actuando con rigor, responsabilidade e ética profesional.

Learning aims
Learning outcomes Study programme competences
1. Conocer de forma completa e integrada os principais mecanismos das reaccións orgánicas. 2. Conocer os principais métodos empregados na determinación do mecanismo de unha reacción en Química Orgánica. 3. Comprender os efectos estereoelectrónicos na reactividade dos compostos orgánicos e en procesos de formación de ciclos. 4. Entender o efecto da conformación dos compostos acíclicos e cíclicos na sua reactividade, y o Principio de Curtin-Hammett. 5. Analizar, de forma integrada, a xeración, a estructura e aa evolución dos intermedios de reacción 6. Profundizar nos principios e nas metodoloxías sintéticas basadas en reaccións pericíclicas. AC1
AC2
AC3
AC6
AC8
BC1
BC2
BC4
BC5
BC7
BC10
BC11
CC1
CC3
CC4

Contents
Topic Sub-topic
1. Determination of reaction mechanisms.

Types of mechanisms. Classification. Determination procedures.
2. Conformational analysis and chemical reactivity.
Thermodynamics of conformations. Implications in reactivity. Influence of the conformations on the result of a reaction.
3. Formation, structure and reactivity of the reaction intermediates.
Types of Intermediates. Classification. Structure of intermediates. Determination procedures. Classification of the reactivity of intermediates
4. Pericyclic reactions. Types of reactions. Characteristics of the polyenic systems.

Planning
Methodologies / tests Competencies Ordinary class hours Student’s personal work hours Total hours
Seminar A1 A2 A3 A6 A8 B1 B2 B4 B5 B7 B10 B11 C1 C3 C4 7 10.5 17.5
Workshop A1 A2 A8 B1 2 3 5
Case study A2 A3 A6 A8 B2 B4 B5 B7 B10 B11 C1 C3 C4 8 8 16
Objective test A3 A6 A8 B1 1 4.5 5.5
Guest lecture / keynote speech A1 A2 A3 A6 A8 B1 12 18 30
 
Personalized attention 1 0 1
 
(*)The information in the planning table is for guidance only and does not take into account the heterogeneity of the students.

Methodologies
Methodologies Description
Seminar Seven interactive sessions will be held, in which students should actively participate in the analysis and resolution of the problems raised by the teacher. The questionnaires of exercises to be solved will be available on the subject's web (moodle) prior to the delivery of the classes. Students should work on the analysis and resolution of problems prior to the delivery of the seminar classes.
Workshop Interactive student problem-solving sessions
Case study Presentation and development of concrete aspects of the contents explained by the teacher, in the form of specific works on specific aspects.
Resolution and commentary on written tests.
Objective test Objective written test of student achievement
Guest lecture / keynote speech 12 lectures are scheduled, in which the teacher will develop the main contents of the program through theoretical explanations, problem solving and practical examples. The content scripts and / or presentations to be developed will be available on the subject's web (moodle) prior to the presentation of the lessons. Based on these materials or on various resources (bibliographies, on the internet ...) students should prepare the lessons in advance to their delivery. The participation of the students will be encouraged, through the elaboration of questions or emails addressed to the professors before, during or after the lesson.

Personalized attention
Methodologies
Workshop
Case study
Description
The students will have personalized attention in the teacher's tutoring schedule to clarify the fundamental concepts of the subject in the large groups, the resolution of individual questions presented in the seminars and in the master sessions.

In addition, the student can receive personalized attention on any aspect of the subject during the teacher's tutoring schedule.

In exceptional, objectivables and properly justified circumstances, the professor may fully or partly exempt any member of the student body to attend the ongoing evaluation process. Students that is in this circumstance must pass a specific test that leaves no doubt about achieving the powers of matter on two occasions.

Assessment
Methodologies Competencies Description Qualification
Guest lecture / keynote speech A1 A2 A3 A6 A8 B1 The active participation of the students will be evaluated by means of the formulation of questions or by e-mail before or after the expositive sessions. 5
Seminar A1 A2 A3 A6 A8 B1 B2 B4 B5 B7 B10 B11 C1 C3 C4 The students' active participation in the analysis and resolution of the problems developed by the teacher will be evaluated, as well as the formulation of questions during interactive sessions or before and after the development of the subject by e-mail. 25
Case study A2 A3 A6 A8 B2 B4 B5 B7 B10 B11 C1 C3 C4 The active participation of students in the resolution of problems touched by the teacher will be evaluated, as well as the formulation of questions during the interactive sessions or before and after the development of the subject by e-mail. 10
Objective test A3 A6 A8 B1 Final written exam, where students will have to solve problems in a limited time and without support materials similar to those presented during the seminar classes and the oral presentation. 60
 
Assessment comments

Evaluation by means of an objective test will contribute to 60% of the final qualification. Attendance
control and continuous assessment (of the work done in the master
sessions, seminars and oral presentations and through the evaluation of
the written solutions of the problem bulletins) will contribute to 30%
of the final qualification. To
obtain APTO qualification it will be necessary to (1) achieve 30% of
the partial qualification scores and (2) achieve 50% of the overall
score. Students
who do not participate in activities that add more than 25% of the
final qualification will be qualified as NOT PRESENTED. Students who perform more than 25% of the face-to-face activities and
after taking the objective tests do not reach 40% of the score in the
same or 50% of the overall score will receive the qualification of NOT
SUITABLE.

In
accordance with the recommendation of the Quality Commission of the
Faculty of Sciences, Honors will be awarded to students who reach the
highest marks at the first opportunity. The students evaluated in the second opportunity will only be eligible
for Honorary Matriculation if the maximum number of these for the
corresponding course was not fully covered at the first opportunity.

In
the case of students with recognition of part-time decision-making and
academic exemption from attendance exemption, the Responsible Professor
may totally or partially exempt from attending the continuous evaluation
process. The
student who is in this circumstance must pass a specific examination
that leaves no doubt about the achievement of the competences of the
subject in the two opportunities.


Sources of information
Basic

Wade, L.G. Química Orgánica, Méxic . Pearson, 2012, QO-437.

Clayden J., Greeves N., Warren S. Organic Chemistry. Oxford University Press 2012, QO-439 .

Complementary


Recommendations
Subjects that it is recommended to have taken before

Subjects that are recommended to be taken simultaneously

Subjects that continue the syllabus

Other comments


(*)The teaching guide is the document in which the URV publishes the information about all its courses. It is a public document and cannot be modified. Only in exceptional cases can it be revised by the competent agent or duly revised so that it is in line with current legislation.