Identifying Data 2017/18
Subject (*) General Chemistry 3 Code 610G01009
Study programme
Grao en Química
Descriptors Cycle Period Year Type Credits
Graduate 2nd four-month period
First FB 6
Language
Spanish
Teaching method Face-to-face
Prerequisites
Department Química
Coordinador
Carlosena Zubieta, Alatzne
E-mail
alatzne.carlosena@udc.es
Lecturers
Alonso Rodriguez, Elia
Carlosena Zubieta, Alatzne
Soto Ferreiro, Rosa Maria
E-mail
elia.alonso@udc.es
alatzne.carlosena@udc.es
rosa.soto.ferreiro@udc.es
Web
General description A materia Química 3 pertence ao módulo de Química, do primeiro curso da titulación de Grao en Química. Nela estúdanse os aspectos máis relevantes dos equilibrios químicos en disolución, que constitúen a base de numerosos procesos da química inorgánica, orgánica, analítica e química física.

Study programme competencies
Code Study programme competences
A1 Ability to use chemistry terminology, nomenclature, conventions and units
A4 Knowledge of main types of chemical reaction and characteristics of each
A5 Understanding of principles of thermodynamics and its applications in chemistry
A6 Knowledge of chemical elements and their compounds, synthesis, structure, properties and reactivity
A7 Knowledge and application of analytical methods
A12 Ability to relate macroscopic properties of matter to its microscopic structure
A16 Ability to source, assess and apply technical bibliographical information and data relating to chemistry
A17 Ability to work safely in a chemistry laboratory (handling of materials, disposal of waste)
A19 Ability to follow standard procedures and handle scientific equipment
A20 Ability to interpret data resulting from laboratory observation and measurement
A21 Understanding of qualitative and quantitative aspects of chemical problems
A23 Critical standards of excellence in experimental technique and analysis
A25 Ability to recognise and analyse link between chemistry and other disciplines, and presence of chemical processes in everyday life
B2 Effective problem solving
B3 Application of logical, critical, creative thinking
B4 Working independently on own initiative
B5 Teamwork and collaboration
C1 Ability to express oneself accurately in the official languages of Galicia (oral and in written)
C3 Ability to use basic information and communications technology (ICT) tools for professional purposes and learning throughout life

Learning aims
Learning outcomes Study programme competences
Knowledge of the nomenclature, structure and reactivity of organic functional groups. Knowledge of chemical equilibrium, entropy, free energy, acid-base, complexation equilibrium, solubility equilibrium, balance and electrochemical redox. A1
A4
A5
A6
A7
A12
A21
A25
B2
B3
C1
C3
Resolution and exposure problems of the chemistry of organic functional groups, the chemical equilibrium and types of chemical reactions (acid-base complex formation, solubility and redox). B2
B3
C1
C3
Skill in the literature search of real applications and research related to the contents of the subject. Have sufficient knowledge and experimental skills to use correctly and safely the products and the usual stuff in a lab. Interpret results obtained in the laboratory. A7
A12
A16
A17
A19
A20
A23
B3
B4
B5
C1
C3

Contents
Topic Sub-topic
Item 1. - Chemistry of organic functional groups. Introduction to organic compounds and structures. Classification, nomenclature and properties of organic compounds as functional groups. Reactivity and main types of organic reactions. Stereoisomerism.
Item 2. - The chemical equilibrium.
General condition of equilibrium. Equilibrium constant. Homogeneous and heterogeneous equilibria. Relationship between kinetics and chemical equilibrium. The reaction quotient. Factors affecting chemical equilibrium. Le Chatelier's Principle. Equilibrium and Gibbs free energy.
Item 3. - Acid-base balance. Acidity and basicity: definition of Arrhenius, Bronsted and Lewis. Autoionization of water. Concept of pH. Strength of acids and bases. Ionization constants. Polyprotic acids. Salt solutions: hydrolysis. Common ion effect. Buffer solutions. Acid-base indicators. Acid-base titration. Acid-base balance in nonaqueous medium. Pearson model.

Item 4. - Balancing complex formation.
General considerations. Types of ligands. Formation and dissociation constants. Acid-base reactions of complex ions. Kinetic aspects. Applications of Coordination Compounds.
Item 5. - Equilibrium solubility. Salt solubility and solubility product. Precipitation reactions and reaction quotient. Fractional precipitation. Factors influencing the solubility of the salts is the common ion effect, effect saline, pH and complexation. Solubility and qualitative analysis.
Item 6. - Redox balance. Oxidation-reduction processes in aqueous solution. Standard electrode potentials. Equilibrium constants for redox reactions. Cell potential and Gibbs free energy. Nernst equation. Mixed equilibria: the influence of other equilibria.
Item 7. - Electrochemistry. Fundamentals of electrochemistry. Electrical conduction. Electrodes. Electrochemical cells. Cell potential and concentration. Electrochemical applications. Electrolysis.

Planning
Methodologies / tests Competencies Ordinary class hours Student’s personal work hours Total hours
Guest lecture / keynote speech A1 A4 A5 A6 A7 A12 A16 A21 A25 B2 B3 B4 24 48 72
Seminar A1 A5 A6 A21 A25 B2 B3 B4 B5 C3 8 24.8 32.8
Laboratory practice A7 A12 A16 A17 A19 A20 A23 B3 B4 B5 C1 C3 20 20 40
Mixed objective/subjective test A1 A4 A5 A6 A20 A21 A25 B3 C1 3 0 3
 
Personalized attention 2 0 2
 
(*)The information in the planning table is for guidance only and does not take into account the heterogeneity of the students.

Methodologies
Methodologies Description
Guest lecture / keynote speech The teacher will present the fundamental contents of each of the topics. For better learning, students will have to advance the development of these sessions teaching materials suitable for your personal preparation. All students can consult the teacher any aspect of the matter in the tutorial schedule established for this purpose. He taught in large group.
Seminar Sessions devoted to the resolution of problems and issues with the active participation of students. He taught in small group.
Laboratory practice In the laboratory sessions students will develop experimental examples of the theoretical exposed in the classroom. Will be essential to achieving the prelaboratorios before the relevant practice (but the student can not perform such practice) as well as keep up to date lab book, according to the instructions of the teacher. An initial meeting will be provided in large group students to explain the content and dynamics of practices.
Mixed objective/subjective test The student will perform a joint test for verifying the degree of understanding of the subject has gained. It will include combined theoretical questions, numerical exercises and questions about the practices.

Personalized attention
Methodologies
Laboratory practice
Seminar
Description
Solving any doubts individually and guiding the student in relation to course content.

Students with recognition of part-time dedication and academic assistance waiver regime will be treated in tutoring (by appointment)

Assessment
Methodologies Competencies Description Qualification
Guest lecture / keynote speech A1 A4 A5 A6 A7 A12 A16 A21 A25 B2 B3 B4 It will assess the student's participation. Some short tests will be done periodically in the seminar sessions and /orguest lecture to assess the evolution of the student. It will be evaluated in conjunction with the seminars. 5
Laboratory practice A7 A12 A16 A17 A19 A20 A23 B3 B4 B5 C1 C3 It will assess the performance of the prelaboratorios, abilities and skills of students in the experimental work, their ability to interpret the results, etc. 20
Seminar A1 A5 A6 A21 A25 B2 B3 B4 B5 C3 It will assess the student's participation, the resolution of problems and numerical excercises, compliance dates for delivery or revision. Some short tests will be done periodically in the seminar sessions and /or guest lecture to assess the evolution of the student. It will be evaluated in conjunction with the guest lectures. 5
Mixed objective/subjective test A1 A4 A5 A6 A20 A21 A25 B3 C1 It has two parts. In one of them will be evaluated the student's ability to express, summarize and develop theoretical aspects of the subject and, in the other, the resolution of problems and numerical exercises. 70
 
Assessment comments

-To pass the subject you must:

   1) Perform the laboratory practices.

   2) Obtain a higher or equal to 5 points rating (out of 10) in the laboratory practices and in each part of the mixed test. If the total sum value was
equal to or greater than 5 (out of 10) but this threshold mark was not met, the
final mark will be 4.5 (fail). The mixed test includes a first part (not compulsory) to evaluate the contents of the first topics of matter; which is eliminatory, so that students who pass it, they do not have to be evaluated from this part at the final exam.

-In the first and second time, students who do practices and obtain less than 5, have the opportunity to, in addition to the mixed test, perform a specific test related to the labs. The score of this test especcífica replaced the grade obtained in practice for the overall rating.


-Students who do not participate in the seminars and keynote speech activities will score 0 in this section (15% of the overall grade) on two occasions. The second time the grade obtained in the course for the overall rating will be maintained.

-
The student will obtain the qualification of No Presented when the
student does not assist to the laboratory practice and neither attend to
the mixed test. As regards the successive academic years, the teaching-learning process, including continuous assessment, refers to an academic course and, therefore, would comezar a new course, including all activities and procedures the Assessment that is scheduled for that course.

- Second Opportunity: The mixed test's mark obtained in the second opportunity  will replace the first one's. The students tested on the second occasion shall be eligible for honors if the maximum number of these to the corresponding course not covered in full at the first opportunity.

Students with recognition of dedication and part-time academic exemption waiver assistance:

Conducting laboratory practices are mandatory and it will be provided within the flexibility to allow coordinating schedules and material and human resources. They shall be deemed exempt from the keynote sessions while assistance will be provided to the greatest number of seminars. If they can not attend the seminars will make a mentored work.


Sources of information
Basic Petrucci, R.H.; Herring, F.G.; Madura, J.D.; Bissonnette, C. (2011). Química General: principios y aplicaciones modernas. 10ª Ed., Prentice Hall, Madrid.

-Previous editions are also recommended textbook Petrucci. For example in the library copies are available from the 8th Ed, with reference: QX-240.

Complementary (). .
Atkins, P.; Jones, L. (2012). Principios de Química. Los caminos del descubrimiento. 5ª Ed., Madrid: Ed. Médica Panamericana.
Reboiras, M.D. (2007). Problemas resueltos de Química. Madrid, Thomson Paraninfo, S.A.
Chang, R. L. (2013). Química. 11ª Ed., México: Mc Graw Hill.
Reboiras, M.D. (2006 ). Química. La ciencia básica . Madrid, Thomson Paraninfo, S.A.

In general any chemistry textbook usually serves as a study guide for the course.


Recommendations
Subjects that it is recommended to have taken before
General Chemistry 1/610G01007
Chemistry Laboratory 1/610G01010

Subjects that are recommended to be taken simultaneously
General Chemistry 2/610G01008

Subjects that continue the syllabus
Analytical Chemistry 1/610G01011
Physical Chemistry 1/610G01016
Inorganic Chemistry 1/610G01021
Organic Chemistry 1/610G01026
Chemistry Laboratory 2/610G01032

Other comments

To successfully overcome the matter, it is imperative that students have a number of prior knowledge of chemistry and mathematics, according to the level required in middle and high school, including: nomenclature and chemical formula, set of chemical reactions , stoichiometric calculations, acid-base character identification of common compounds, obtaining oxidation states of the elements in the chemical species, management of logarithms, exponents, etc..



(*)The teaching guide is the document in which the URV publishes the information about all its courses. It is a public document and cannot be modified. Only in exceptional cases can it be revised by the competent agent or duly revised so that it is in line with current legislation.