Attendance at all seminars and practices is compulsory for the student to pass the course.

First opportunity assessment:

The
student pass the subject when the average of the marks obtained in the different methodologies of assessment is equal to or greater than 5.0 points out of 10 and the mark obtained in the written test is equal or greater than 3.5 points out of 10.

The student fail the subject in case of not achieving the minimum mark in the written test
(3.5), although the average of the assessment methodologies was equal to or
greater than 5.0. The subject appears as failed (4.5).

The final mark could be scaled up to a maximum of 0.5 points as a result of the evaluation of the overall student's progression.

A grade of NP ("absent") will only be given to the students who do not engage in any practice session in the lab.

Second opportunity assessement:

Students who do
not pass the continuous assessment of the practical work in the
laboratory must pass an experimental test at the lab.

The
students who pass the continuous assessment of the practical work in
the laboratory will have to pass a test in the classroom that will represent 100% of the final grade.

Students evaluated in the "second opportunity" will only be eligible for
Honors if the maximum number of licenses for the corresponding course
has not been fully covered in the "first opportunity"

Should it be more candidates to honors grade than licenses available, allocation of licenses could be done through a extraordinary exam.

The teaching-learning process, including assessment, refers to an
academic course and, therefore, will restart as new with every new
academic year, including all activities and assessment procedures
scheduled for that course.

Part-time students and students with special academic permission (according to the rules of the UDC):

Being an experimental subject, assistance to all activities is mandatory. As far as possible, it will be tried to fit the schedule of the practical sessions to the availability of students.

The evaluation criteria for both the first and the second opportunity, will be the same as for the rest of the students.

Learning outcomes	Study programme competences
To acquire practical skills needed for experimental quantification of the thermodynamic and electrochemical properties of chemical systems.	A17 A18 A19 A22	B2 B3	C3
To acquire skills in the treatment of the measurements in the laboratory and skill in the use of software to carry out the analysis of experimental data.	A20 A21 A22	B2 B3
To acquire practical skills in the application of instrumental techniques most commonly used in chemistry to the study of systems of physicochemical interest.	A19 A22	B2 B3
To analyze and interpret the result of a chemical experiment from fundamental theoretical concepts of Physical Chemistry.	A5 A14 A20 A21 A22	B2 B3
To write a comprehensive report of experimental work using appropriate scientific language.	A1 A16 A20	B3 B4	C1 C3
To learn how to search, use and cite required bibliographic information.	A16	B4 B5	C3

Topic	Sub-topic
Chemical Thermodynamics practical demonstrations that do not require instrumental techniques	1. Partial molal volumes of a binary mixture. 2. Molecular masses by cryoscopy measurements. 3. Activity of an electrolyte by cryoscopy measurements. 4. Molecular masses by distillation of mixture of two immiscible liquids. 5. Phase diagram of a ternary system. 6. Determination of the equilibrium constant. 7. Determination of heat of solution for benzoic acid by solubility measurements. 8. Partition coefficient. Application to the calculation of an equilibrium constant. 9. Determination of the solubility of a compound sparingly soluble in several saline media. Common ion effect and salting effect. 10. Chemical equilibrium. Determination of DG0, DH0 and DS0. 11. Diagram of solid-liquid phase of a binary system.
Chemical Thermodynamics practical demonstrations that incorporate instrumental techniques	12. Determination of the phase diagram of a vapor-liquid binary system. 13. Spectrophotometric determination of the equilibrium constant of an indicator. 14. Characterization of a coordination compound by spectrophotometric measurements. 15. Potentiometric determination of the dissociation product of water by Gran's method. 16. Dye adsorption isotherms.

Methodologies / tests	Competencies	Ordinary class hours	Student’s personal work hours	Total hours
Seminar	A5	4	3	7
Laboratory practice	A1 A14 A16 A17 A18 A19 A20 A22 B3 B4 B5 C1 C3	56	84	140
Mixed objective/subjective test	A1 A5 A14 A20 A21 B2 B3 C3	3	0	3

Personalized attention		0		0

(*)The information in the planning table is for guidance only and does not take into account the heterogeneity of the students.

Methodologies	Description
Seminar	Practical experiments to perform are proposed. These experiments are related to the theoretical contents of Physical Chemistry 3 subject. Different experimental methodologies are proposed and a specific experimental procedure is discussed.
Laboratory practice	Each student is assigned a certain number of practical experiments to be performed individually. The experiments will be indicated in advance in order to prepare both the theoretical background and experimental procedure before going into the lab. During the laboratory work, the student must show a responsible attitude in relation with both the safety regulations and the methodology and rigour of the scientific method. The experimental results of each experiment should be analyzed and discussed adequately, being neccesary the use of computer resources. Each student must hand in a written report of each of the experiments done. This report must contain all the experimental data, its analysis and the critical discussion of the results obtained. The report must be written following the guidelines of a scientific report.
Mixed objective/subjective test	Assessment of all the contents worked on the subject, both the theoretical background and the experimental contents, related with the procedure, the analysis of data and the discussion of the results.

Methodologies	Competencies	Description	Qualification
Laboratory practice	A1 A14 A16 A17 A18 A19 A20 A22 B3 B4 B5 C1 C3	The assessment of laboratory practices includes: 1) Continuous assessment of the work done by the student in the laboratory, considering the skills and knowledge achieved, the answers to the questions made during the lab, as well as the experimental data, its analysis and discussion. The lack of knowledge and/or attitude during the experimental work in the lab will be reason for expulsion from the lab. It is compulsory to complete the whole period of laboratory sessions to pass the subject. 2) The report prepared for each one of the experiments carried out, which must include all the experimental data, its analysis and the critical discussion of the results obtained. In addition, the report must be written following the guidelines of a scientific report.	50
Mixed objective/subjective test	A1 A5 A14 A20 A21 B2 B3 C3	Written test to evaluate the contents of the subject, both the theoretical background of the experiments and the analysis and discussion of the experimental results. It constitutes 50% of the final grade at the first opportunity, but students must obtain a minimum of 3.5 points out of 10 in the written test to pass the course. In the second opportunity, the written test will represent 100% of the final grade.	50

Assessment comments
Attendance at all seminars and practices is compulsory for the student to pass the course. First opportunity assessment: The student pass the subject when the average of the marks obtained in the different methodologies of assessment is equal to or greater than 5.0 points out of 10 and the mark obtained in the written test is equal or greater than 3.5 points out of 10. The student fail the subject in case of not achieving the minimum mark in the written test (3.5), although the average of the assessment methodologies was equal to or greater than 5.0. The subject appears as failed (4.5). The final mark could be scaled up to a maximum of 0.5 points as a result of the evaluation of the overall student's progression. A grade of NP ("absent") will only be given to the students who do not engage in any practice session in the lab. Second opportunity assessement: Students who do not pass the continuous assessment of the practical work in the laboratory must pass an experimental test at the lab. The students who pass the continuous assessment of the practical work in the laboratory will have to pass a test in the classroom that will represent 100% of the final grade. Students evaluated in the "second opportunity" will only be eligible for Honors if the maximum number of licenses for the corresponding course has not been fully covered in the "first opportunity" Should it be more candidates to honors grade than licenses available, allocation of licenses could be done through a extraordinary exam. The teaching-learning process, including assessment, refers to an academic course and, therefore, will restart as new with every new academic year, including all activities and assessment procedures scheduled for that course. Part-time students and students with special academic permission (according to the rules of the UDC): Being an experimental subject, assistance to all activities is mandatory. As far as possible, it will be tried to fit the schedule of the practical sessions to the availability of students. The evaluation criteria for both the first and the second opportunity, will be the same as for the rest of the students.

Basic	Ruix Sánchez, J.J.; Rodríguez Mellado, J.M.; Muñoz Gutiérrez, E., Sevilla Suárez de Urbina, J.M. (2003). Curso experimental en Química Física. Síntesis Denbigh, K. (1985). Equilibrio Químico . Madrid. AC Matthews, G.P (1985). Experimental Physical Chemistry. Boston. Oxford Science Pub Shoemaker, D.P.; Garland, G.W.; Nibler, J.W. (2009). Experiments in Physical Chemistry 8ª ed.. McGraw-Hill Levine, I.N. (2004). Fisicoquímica . McGraw-Hill Sime, R.J (1990). Physical Chemistry: Methods, techniques, experiments.. Philadelphia. Saunders College Publishing
	- M. S. Robinson F. L. Stoller, B. Horn, and W. Grabe "Teaching and Applying Chemistry-Specific Writing Skills Using a Simple, Adaptable Exercise" J. Chemical Education, 86, 45, (2009) -D. C. Harris. "Nonlinear least-squares curve fitting with Microsoft Excel Solver" J. Chemical Education, 75, 119 (1998)
Complementary	Sime, R.J. (2005). Physical chemistry calculations with Excel, Visual Basic, Visual Basic with applications, Mathcad, Mathmatica. San Francisco: Pearson

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