Identifying Data 2020/21
Subject (*) Advanced Inorganic Chemistry Code 610G01025
Study programme
Grao en Química
Descriptors Cycle Period Year Type Credits
Graduate 1st four-month period
Fourth Obligatory 6
Language
Spanish
English
Teaching method Hybrid
Prerequisites
Department Química
Coordinador
Fernandez Sanchez, Jesus Jose
E-mail
jesus.fernandezs@udc.es
Lecturers
Fernandez Lopez, Alberto A.
Fernandez Sanchez, Jesus Jose
E-mail
alberto.fernandez@udc.es
jesus.fernandezs@udc.es
Web
General description O estudo da Química Inorgánica dividiuse en grandes campos, un das cales é a Química Organometálica, disciplina que aborda a investigación experimental e o tratamento da estrutura, enlace, propiedades, reactividade e aplicacións dos compostos con enlace M-C. A súa importancia e interese va mais alá dos límites puramente académicos, posto que na química moderna distínguense infinidade de compostos organometálicos que se utilizan habitualmente ou están implicados en numerosos procesos sintéticos, a nivel molecular ou catalítico, así como en procesos industriais e tecnolóxicos.
A materia "Química Inorgánica Avanzada", situada no primeiro semestre de cuarto curso do Grao en Química pola UDC, está dedicada ao estudo dos compostos organometálicos, e constitúe unha materia mixta que consta de 4 créditos teóricos e 2 créditos prácticos.
Contingency plan 1. Modificacións nos contidos
Non hay modificación
2. Metodoloxías
*Metodoloxías docentes que se manteñen
Se manteñen todas as metodoloxías
*Metodoloxías docentes que se modifican
As actividades de “sesión maxistral e solución de problemas” manterán o mesmo formato e contidos coa única diferencia de que serán impartidas utilizado Teams ou a plataforma que a UDC poña a disposición da comunidade docente.
O único cambio abranguera as sesións presenciais da metodoloxía “prácticas de laboratorio” que, no caso de que non poidan ser impartidas de forma presencial, serán substituídas por actividades on line dedicadas á obtención e caracterización de compostos organometálicos. O resto das actividades relacionadas con esta metodoloxía poderán ser impartidas de forma sincrónica ou asincrónica utilizando as plataformas de teleformación Moodle e Teams ou outras que a UDC poña a disposición da comunidade.
3. Mecanismos de atención personalizada ao alumnado
Correo electrónico, a demanda do alumno.
Teams, a petición do alumno, excepto no perído de actividades relacionadas coas prácticas de laboratorio, no que se convocará, polo menos, unha tutoría obrigatoria por alumno.
Moodle, a petición dos alumnos.

4. Modificacións na avaliación
Non haberá modificación nin na metodoloxía nin nos porcentaxes asignados a cada una das metodoloxías.
*Observacións de avaliación:
Manterase a avaliación tal y como figura en la guía docente. A única diferencia será na canle utilizada para as probas que pasará a ser Teams ou Moodle ou unha combinación das mesmas.
5. Modificacións da bibliografía ou webgrafía
Non haberá cambios na bibliografía e recursos web referenciados en Moodle e na Guía Docente da materia. Non obstante, a asistencia as diferentes actividades docentes e o material dispoñible en Moodle serán suficientes para superar a materia.

Study programme competencies
Code Study programme competences
A1 Ability to use chemistry terminology, nomenclature, conventions and units
A4 Knowledge of main types of chemical reaction and characteristics of each
A6 Knowledge of chemical elements and their compounds, synthesis, structure, properties and reactivity
A9 Knowledge of structural characteristics of chemical and stereochemical compounds, and basic methods of structural analysis and research
A10 Knowledge of chemical kinetics, catalysis and reaction mechanisms
A14 Ability to demonstrate knowledge and understanding of concepts, principles and theories in chemistry
A16 Ability to source, assess and apply technical bibliographical information and data relating to chemistry
A17 Ability to work safely in a chemistry laboratory (handling of materials, disposal of waste)
A18 Risk management in relation to use of chemical substances and laboratory procedures
A20 Ability to interpret data resulting from laboratory observation and measurement
A22 Ability to plan, design and develop projects and experiments
A23 Critical standards of excellence in experimental technique and analysis
A26 Ability to follow standard laboratory procedures in relation to analysis and synthesis of organic and inorganic systems
B1 Learning to learn
B2 Effective problem solving
B3 Application of logical, critical, creative thinking
B4 Working independently on own initiative
C1 Ability to express oneself accurately in the official languages of Galicia (oral and in written)
C2 Oral and written proficiency in a foreign language

Learning aims
Learning outcomes Study programme competences
Students should know the structure, nature of bonding, reactivity and properties of organometallic complexes and apply this knowledge to the solution of chemical problems. A1
A4
A6
A9
A10
A14
A16
B1
B2
B3
B4
C1
C2
Students should be able to apply the theoretical knowledge and practical skills necessary to carry out the synthesis and characterization of organometallic compounds. A1
A9
A14
A16
A17
A18
A20
A22
A23
A26
B1
B2
B3
B4
C1
C2

Contents
Topic Sub-topic
I. Organometallic chemistry. I.I. General characteristics of organometallic compounds.
I.II. Organometallic compounds in the main groups.
I.III. Reaction mechanisms of inorganic species.
II. Organometallic compounds with monohapto lygands. II.I. Metal carbonyls.
II.II. Organometallic compounds with monohapto ligands: sigma M-C bond.
II.III. Metal carbenes and carbines.
III. Organometallic compounds with polyhapto ligands. III.I: Organometallic compounds with dihapto ligands: akenes and alkynes.
III.II: Organometallic compounds with trihapto ligands: allyls.
III.III. Organometallic compounds with tetrahapto ligands: conjugated diolefins.
III.IV. Organometallic compounds with pentahapto ligands: cyclopentadienyls.
III.V. Organometallic compounds with hexahapto ligands: arenes.
IV. Experimental organometalllic chemistry. IV.I. Syntheses of organometallic compounds.
IV.II. Structural determination applied to organometallic compounds.

Planning
Methodologies / tests Competencies Ordinary class hours Student’s personal work hours Total hours
Guest lecture / keynote speech A14 B3 C1 C2 21 42 63
Problem solving A1 A4 A6 A9 A10 A14 A16 B1 B2 B3 C1 C2 7 14 21
Laboratory practice A1 A4 A6 A9 A16 A17 A18 A20 A22 A23 A26 B1 B4 20 20 40
Mixed objective/subjective test A1 A4 A6 A9 A10 A14 B2 B3 C1 C2 4 22 26
 
Personalized attention 0 0 0
 
(*)The information in the planning table is for guidance only and does not take into account the heterogeneity of the students.

Methodologies
Methodologies Description
Guest lecture / keynote speech Lectures dedicated to introduce the most relevant contents of the course. Active participation of students are encouraged as an important part of the lectures methodology.
Prior to each lecture students are supposed to have read the suggested readings related to the topics of the lecture. If necessary the students are expected to prepare by themselves part of the course contents in the student’s personal work hours.
Problem solving Classes given in small groups of students, which must participate actively. Problem-solving classes are dedicated to solving the doubts arisen during lectures and the preparatory readings. They are also dedicated to the resolution of problems and questions previously given to the students or to the intensive study of a particular topic through the active discussion methodology. If necessary, practical cases may also be solved using the university Moodle.
Laboratory practice Laboratory classes which are dedicated to the synthesis, isolation and characterization of organometallic compounds.
Prior to the lab class, the student studies the theoretical and synthetic aspects of each laboratory experiment using the recommended bibliographic sources. Before starting the laboratory work, the student has to show, in a personal tutorial with the professor, that has reached the necessary level of knowledge and skills necessary to understand and carry out the experiment safely. During the laboratory work, the student must work carefully paying special attention to the safety rules and showing the rigor and efficiency characteristic of the scientific method. The preparatory work, the experimental description (laboratory diary) and the conclusions drawn must be recorded in the laboratory notebook, which must be given to the professor before the deadline.
Mixed objective/subjective test The mixed test is a written exam, which consists of essay-type questions in which the student must find the answer to a more or less complex problem, which may be of logic or numeric nature. It may also contain objective test questions.

Personalized attention
Methodologies
Guest lecture / keynote speech
Problem solving
Laboratory practice
Mixed objective/subjective test
Description
Personalized attention is aimed to give support to the students in the process of autonomous learning. The tutorials are organized by the professor and dedicated to the solution of doubts related to the contents of this subject or arisen during the preparation of the problem-solving sessions; but, especially during the preparation of the laboratory practice classes.
Part-time students (according to the UDC regulations) will be given personalized tutorial support:
The students will be given tutorial support according to their needs at any moment.
Particularly, those students will be periodically given handouts with problems and questions designed to gauge the acquisitions of competencies. The students will solve those problems individually and, after this, attend to a tutorial to solve doubts and correct the problems.
On request, the students will also be given tutorial support in order to prepare the laboratory experiments.

Assessment
Methodologies Competencies Description Qualification
Guest lecture / keynote speech A14 B3 C1 C2 During lectures, the professor assesses the active participation of students as well as their reasoning and oratory skills.
If necessary, the students might take a brief test consisting of short answer or multiple election questions, during the lecture hours. The solution and presentation of a study case using Moodle are also possible. The marks corresponding to these activities will be added to the “problem solution” marks.
0
Problem solving A1 A4 A6 A9 A10 A14 A16 B1 B2 B3 C1 C2 During the problem-solving classes, the professor assesses the active participation of students as well as their reasoning and oratory skills.
If necessary, the students might take a brief test consisting of short answer or multiple election questions, during the lecture hours. The solution and presentation of a study case using Moodle are also possible. The marks corresponding to these activities will be added to the “lecture” marks.
20
Laboratory practice A1 A4 A6 A9 A16 A17 A18 A20 A22 A23 A26 B1 B4 During the pre-lab tutorial, the professor assess the rigorous preparation of the theoretical and experimental parts of the laboratory experiment which concerns both the synthetic and the characterization methodology.
The professor also assesses the laboratory work, particularly: the organization, safety work, knowledge of the material and technical procedures, the manual skill and, especially, the ability to find relationships between the experimental procedure carried out and the theoretical background acquired during the previous work.
The laboratory notebook will also be marked. It consists of four parts: preparatory work, exact description of laboratory work (laboratory diary), characterization of the products synthesized and results and conclusions drawn from the experiment.
20
Mixed objective/subjective test A1 A4 A6 A9 A10 A14 B2 B3 C1 C2 Students will take the mixed test in the hours designed by the Faculty. The assessment criteria will be given before the exam. 60
 
Assessment comments

In order to pass the subject, the students must attend to all the laboratory classes and to the 80% of the remaining activities.

In the “first opportunity”, the contribution of the different methodologies to the final assessment is as follows:

C1 Mixed text, 6.0 points.

C2 Laboratory practice, 2.0 points

C3 Keynote speech + problem solving + short test, 2.0 points.

C4 Student progression, 1 point.

In order to pass the subject the students have to attain a minimum mark of 5 points corresponding to the sum of (C1 + C2+ C3) and comply with the following requirements:

The student must attain a minimum of the 45% of the maximum mark in contributions C1 and C2. If the sum (C1 + C2+ C3) is 5 points or higher but C1 and C2 do not reach the 45% threshold, the final mark will be 4.5 points.

The contribution C4 “Student progression” will be added to the final marks only if the sum C1 + C2+ C3 is 5 or more points. (In any case, the maximum mark is 10 points)

The condition of “no presentado” will be granted to those students who have participated in activities summing less than the 20% of the total mark.

In the “second opportunity”, the student repeats only of the mixed test. The marks corresponding to laboratory practice, and keynote speech + problem solving + short test are those attained during the normal period of classes (first opportunity). The contribution of each methodology and the conditions to pass the subject are the defined for the first opportunity. Consequently, a minimum mark of 45% in laboratory practice (C1) in the first opportunity is also necessary to pass the subject in the second opportunity.

The mark “matricula de honor” will be granted preferably to the students that have passed the subject in the first opportunity.

Attendance to laboratory practice classes is mandatory for part-time students (according to the UDC regulations). For those students, the contribution to the final marks is as follows: 75% of the final marks corresponds to the mixed text and the remaining 25% corresponds to the laboratory practice. The marking system (percentages) will be the same for both opportunities. The condition of “no persentado” will be granted to those part-time students who do not take the mixed text.


Sources of information
Basic C. Elschenbroich (2006). Organometallics. Weinheim, Wiley-VCH
A.F. Hill (2002). Organotransition metal chemistry. Cambridge, Royal Soc. of Chem.
R.H. Crabtree (2009). The organometallic chemistry of the transition metals. New Jersey, Wiley

Specific bibliographic sources for the work (synthesis and characterization) in an Inorganic Chemistry Lab are available in the Faculty Library.

Complementary G.A. Carriedo Ule y D. Miguel Sanjosé (1995). Iniciación a la química organometálica. Oviedo, Pub. Univ. Oviedo
G.O. Spessard y G.L. Miessler (2010). Organometallic Chemistry. New York, Oxford Univ. Press
D. Astruc (2003). Química organometálica. Barcelona, Reverté
R.H. Crabtree y E. Peris Fajarnés (1997). Química organometálica de los metales de transición. Castellon, Pub. Univ. Jaume I

"Organometallic Hypertext Book", R.

Toreki

(ILPI, Interactive Learning Paradigms Incorporated) available at http://www.ilpi.com/organomet/


Recommendations
Subjects that it is recommended to have taken before
Inorganic Chemistry 1/610G01021
Inorganic Chemistry 2/610G01022
Inorganic Chemistry 3/610G01023
Inorganic Chemistry 4/610G01024

Subjects that are recommended to be taken simultaneously

Subjects that continue the syllabus

Other comments

The subject “Advanced Inorganic Chemistry” is the last compulsory subject corresponding to Inorganic Chemistry in the Chemistry Degree therefore, is highly recommendable to have passed the previous “Inorganic Chemistries 1-4”.

Complementary material will be given to the students through the Moodle.

It is highly advisable to attend all classes and the active participation in all activities.



(*)The teaching guide is the document in which the URV publishes the information about all its courses. It is a public document and cannot be modified. Only in exceptional cases can it be revised by the competent agent or duly revised so that it is in line with current legislation.