Identifying Data 2019/20
Subject (*) Organic Chemistry 1 Code 610G01026
Study programme
Grao en Química
Descriptors Cycle Period Year Type Credits
Graduate 1st four-month period
Second Obligatory 6
Language
Spanish
English
Teaching method Face-to-face
Prerequisites
Department Química
Coordinador
Ruiz Pita-Romero, Maria
E-mail
maria.ruiz.pita-romero@udc.es
Lecturers
Ojea Cao, Vicente
Pazos Chantrero, Elena
Ruiz Pita-Romero, Maria
E-mail
vicente.ojea@udc.es
elena.pazos@udc.es
maria.ruiz.pita-romero@udc.es
Web http://campusvirtual.udc.es/moodle/
General description A materia pretende proporcionar os coñecementos básicos de Química Orgánica ao alumno do Grao en Química.

Study programme competencies
Code Study programme competences
A1 Ability to use chemistry terminology, nomenclature, conventions and units
A4 Knowledge of main types of chemical reaction and characteristics of each
A6 Knowledge of chemical elements and their compounds, synthesis, structure, properties and reactivity
A9 Knowledge of structural characteristics of chemical and stereochemical compounds, and basic methods of structural analysis and research
A10 Knowledge of chemical kinetics, catalysis and reaction mechanisms
A14 Ability to demonstrate knowledge and understanding of concepts, principles and theories in chemistry
A15 Ability to recognise and analyse new problems and develop solution strategies
A21 Understanding of qualitative and quantitative aspects of chemical problems
B2 Effective problem solving
B3 Application of logical, critical, creative thinking
B4 Working independently on own initiative
C1 Ability to express oneself accurately in the official languages of Galicia (oral and in written)
C3 Ability to use basic information and communications technology (ICT) tools for professional purposes and learning throughout life

Learning aims
Learning outcomes Study programme competences
Understand and know basic concepts, principles and theories related to Organic Chemistry A1
A4
A6
A9
A10
A14
A15
A21
B2
B3
B4
C1
Use Organic Chemistry terminology, including nomenclature, main conventions, and units A1
A6
A9
A14
B2
B3
C1
C3
Know the caracteristics and propierties of organic compounds. A1
A9
A14
A21
B2
B3
Adquire the ability to solve estructural and synthetic problems in Organic Chemistry through the analysis of the present functional groups and the application of the acquired knowledge regarding their properties and reactivity A1
A4
A9
A14
A15
A21
B2
B3
B4
C3
Know the main types of organic reactions, their mechanistic pathways and their main stereochemical features. A1
A4
A6
A9
A10
A21
B2
B3
B4
C1
C3
Acquire the ability to use literature, as well as to search for specific information in Organic Chemistry A6
A9
A14
B3
B4
C1
C3

Contents
Topic Sub-topic
Unit 1. Structure and reactions of organic compounds Characteristics, structure and bonding of organic compounds: functional groups, Lewis structures, hybrid atomic orbitals, resonance. Organic Reactions: classification, types of reagents, types of reaction mechanisms. Thermodynamic and kinetic features of organic reactions. Kinetic and thermodynamic control. Reaction intermediates.
Unit 2. Stereoisomerism Nomenclature, properties and isomerism of alkanes. Constitutional isomerism and stereoisomerism. Conformational isomerism: conformational analysis of alkanes and cycloalkanes, Newman projections. Optical isomerism, chirality and symmetry. Enantiomers and diastereoisomers: nomenclature, Fischer projections. Resolution of racemic mixtures.
Unit 3. NMR Spectroscopy Basic principles of the NMR. Most important nuclei in Organic Chemistry. Chemical shift, Spin-spin coupling: N+1 rule. Identification of functional groups by NMR.
Unit 4. Alkanes Halogenation, pyrolysis, cracking, combustion.
Unit 5. Alkyl Halides Nomenclature, structure and properties. Nucleophilic substition reactions (SN): factors determinig the mechanism of nucleophilic substitutions: substrate (structure of the alkyl group and nature of the leaving group), nucleophilicity of the reagent and solvent effects. Elimination reactions. Competitive proccesses in the SN reaction: transpositions and eliminations. Organometallic compounds. Reduction of alkyl halides.
Unit 6. Alcohols Nomenclature, structure and properties. Acid-base behavior. O-H bond reactions. C-O bond reactions. Oxidation. Thiols.
Unit 7. Ethers Nomenclature, structure and properties. Ether cleavage. Epoxides. Thioethers.
Unit 8. Amines Nomenclature, structure and properties. Acid-base reactions. Alkylation of amines. Hofmann's elimination. Oxidation: Cope's elimination.

Planning
Methodologies / tests Competencies Ordinary class hours Student’s personal work hours Total hours
Guest lecture / keynote speech A1 A4 A6 A9 A10 20 30 50
Seminar A1 A4 A6 A9 A10 10 25 35
Workshop A1 A4 A6 A9 A10 B4 B2 C1 10 30 40
ICT practicals A6 A9 A21 B2 B4 C3 10 10 20
Mixed objective/subjective test A1 A4 A6 A9 A10 A14 A15 A21 B2 B3 C1 4 0 4
 
Personalized attention 1 0 1
 
(*)The information in the planning table is for guidance only and does not take into account the heterogeneity of the students.

Methodologies
Methodologies Description
Guest lecture / keynote speech The teacher will present the fundamental contents of each subject that will be previously provided to the students in order to prepare them on their own before the class. With the help of these materials and other bibliographic resources, students must prepare the lessons before the lectures. The participation of the students will be encouraged, with the intention that questions will be asked during the lesson (or before or afterwards by e-mail)
Seminar Sessions dedicated to solving problems and questions with an active participation of the student. Problems to be resolved will be available on Moodle platform before the seminars. Students must work on the problems before the seminars.
Workshop The workshops are work sessions organized in small groups. The teacher will assign the students the preparation of some problems, which may require the integration of contents from different units. Students must prepare and hand in solutions for the assigned problems before the workshops. During the workshop sessions the students will present the problems and answer the questions that arise.
ICT practicals Practicals will be fundamentally focused on two aspects: (1) the two and/or three-dimensional representation of organic compounds through the use of computational tools, aimed at the analysis and resolution of stereochemistry problems; (2) the structural determination of organic compounds based on 1H NMR with the support of spectra simulation programs.
Mixed objective/subjective test In order to evaluate the knowledge and the ability to apply the subject contents by the student, a mixed test is scheduled. The test will include questions and problems analogous to those solved in the seminar and workshop sessions during the course, related to nomenclature, structure, structural determination, reactivity and synthesis of organic compounds.

Personalized attention
Methodologies
ICT practicals
Workshop
Description
Students will have the assistance from the teacher during tutorials (in addition to the classroom activities) for the resolution of doubts and questions that may arise from the study of contents, the preparation of the solution report for the workshops or the final report in the ICT practices. Personalized attention will be also supported by e-mail.
For the students with recognition of part-time dedication or in specific modalities of learning or supporting to diversity, personalized attention will be provided with all the flexibility that the coordination schedules and the material and human resources available can offer.


Assessment
Methodologies Competencies Description Qualification
Mixed objective/subjective test A1 A4 A6 A9 A10 A14 A15 A21 B2 B3 C1 It will take place during the official examination period, on the dates established by the Center. The test will consist of a written exercise with problems and questions analogous to those solved in the seminars, workshops and practicals.
75
ICT practicals A6 A9 A21 B2 B4 C3 The participation in the practicals will contribute with a 5% to the evaluation.
The students will prepare a final report on the exercises of the practices that will contribute with another 5% to the evaluation.
10
Workshop A1 A4 A6 A9 A10 B4 B2 C1 The quality of the written solutions that had been handed in in advance will be evaluated, as well as the participation during the workshops by means of the formulation of questions or answers. During the presentation of the problems, the use of the appropriate nomenclature for compounds and reactions, the clarity and specification of the explanations and the answers to the questions that arise will be evaluated. 15
 
Assessment comments

The assistance to the ICT practicals is an essential requirement to pass the course. To pass the subject it is necessary to obtain in the mixed test a note equal to or greater than 5. Therefore, students with a global grade equal to or greater
than 5 who have not reached the qualification of 5 in the mixed test will be
graded as not pass (grade of 4.5). Students who have not completed the practicals and have not carried out the mixed test will get the No Presented qualification.

The qualifications of the laboratory practicals and the workshops will be maintained at the second opportunity. Therefore,
in the second opportunity students will take only the mixed test,
whose qualification will replace the one obtained in the mixed test of the
first opportunity. The students evaluated in the second opportunity will only be
eligible for the Honored Grade (Matrícula de Honor) if the maximum number of
these for the corresponding course has not been covered in full at the
first opportunity.

Students with recognition of part-time dedication
will be evaluated with the criteria listed above.

Students with special academic permission could be exempted
from the workshops attendance (15% of the overall grade) and could be
evaluated by means of ICT practicals and
the mixed test, both in the first and second opportunity. For those
students who took advantage of the workshop attendance waiver, the mixed test
will contribute to 90% of the overall score. The attendance to the ICT practicals is mandatory to pass the subject and it will be facilitated within the flexibility
that the coordination schedules and the material and human resources available
can offer. In the case of exceptional, objectivable and adequately justified
circumstances, the QO1 coordinator could exempt a student from attending the
process of continuous evaluation of ICT practicals. The student who is in
this circumstance must pass a specific examination (corresponding to 100% of
the grade) precluding any doubt about the achievement of the knowledge, skills
and competences of the subject.


Sources of information
Basic E. QUIÑOÁ y R. RIGUERA (2004). CUESTIONES Y EJERCICIOS DE QUÍMICA ORGÁNICA (2ª ed). Madrid, McGraw-Hill
T. W. G. Solomons, C. B. Fryhle (2008). Organic Chemistry. John Wiley & Sons
K.P.C. VOLLHARDT and N.E. SCHORE (2011). Organic Chemistry 6th eddition. WH Freeman and Company
L.G. WADE, Jr. (2004). QUÍMICA ORGÁNICA (5ª ed). Madrid, Pearson Educación
K. P. C. Vollhardt, N. E. Schore (2007). Química Orgánica: estructura y función. Omega

Complementary


Recommendations
Subjects that it is recommended to have taken before
General Chemistry 1/610G01007
General Chemistry 2/610G01008
General Chemistry 3/610G01009
Chemistry Laboratory 1/610G01010

Subjects that are recommended to be taken simultaneously

Subjects that continue the syllabus
Organic Chemistry 2/610G01027
Intermediate Organic Chemistry/610G01028
Experimental Organic Chemistry/610G01029
Advanced Organic Chemistry/610G01030

Other comments

We highly recommend as main sources of information the books: Wade 2004 and Vollhardt, 2007. We also recommend the reading of the main subjects of each topic, as preparation to the teacher's keynote lectures.



(*)The teaching guide is the document in which the URV publishes the information about all its courses. It is a public document and cannot be modified. Only in exceptional cases can it be revised by the competent agent or duly revised so that it is in line with current legislation.