Ampliación de Química Orgánica é unha materia do módulo de Química Orgánica, que se orienta ao estudo da nomenclatura, a estrutura, as propiedades, a reactividade e os principais métodos de síntese de derivados de ácidos carboxílicos, enoles e enolatos, compostos orgánicos difuncionales, con nitróxeno en ligazóns múltiples, con aneis heterocíclicos ou con importancia biolóxica, como os carbohidratos, os aminoácidos, os péptidos e os ácidos nucleicos.
Contingency plan
1. Modificacións nos contidos
Non habrá ninguna modificación
2. Metodoloxías
*Metodoloxías docentes que se modifican
Actividades iniciais, Sesión maxistral, Seminarios a través de Teams
Proba final escrita non presencial online, onde os alumnos deberán resolver en tempo limitado, problemas análogos aos expostos durante as clases de seminario e presentación oral. O exame será escrito a entregar na misma plataforma de Teams.
3. Mecanismos de atención personalizada ao alumnado
Tutorías e resolución de dudas mediante Teams.
Preguntas mediante correo electrónico
Observacións de avaliación:
Exame 70%. Proba final escrita non presencial online, onde os alumnos deberán resolver en tempo limitado, problemas análogos aos expostos durante as clases de seminario e presentación oral.
Seminarios e participación na clase (25 %+5 %) Cualificación obtida na avaliación continua durante o primeiro cuadrimestre poderá conservarse na segunda oportunidade.
Study programme competencies
Code
Study programme competences
A1
Ability to use chemistry terminology, nomenclature, conventions and units
A4
Knowledge of main types of chemical reaction and characteristics of each
A6
Knowledge of chemical elements and their compounds, synthesis, structure, properties and reactivity
A9
Knowledge of structural characteristics of chemical and stereochemical compounds, and basic methods of structural analysis and research
A10
Knowledge of chemical kinetics, catalysis and reaction mechanisms
A14
Ability to demonstrate knowledge and understanding of concepts, principles and theories in chemistry
A15
Ability to recognise and analyse new problems and develop solution strategies
A21
Understanding of qualitative and quantitative aspects of chemical problems
A25
Ability to recognise and analyse link between chemistry and other disciplines, and presence of chemical processes in everyday life
B2
Effective problem solving
B3
Application of logical, critical, creative thinking
B4
Working independently on own initiative
C1
Ability to express oneself accurately in the official languages of Galicia (oral and in written)
C8
Understanding role of research, innovation and technology in socio-economic and cultural development
Learning aims
Learning outcomes
Study programme competences
Resolution and exposure problems associated with the structure, reactivity and the synthesis of difunctional organic compounds with nitrogen multiple bonds, or heterocyclic important biological nature such as carbohydrates, amino acids, peptides and nucleic acids.
A1 A4 A6 A9 A14 A15 A25
B2 B3 B4
C1 C8
Knowledge of nomenclature, structure, properties, reactivity and the main methods for the synthesis of: carbonyl compounds, difunctional compounds, compounds containing multiple bond with nitrogen, heterocyclic compounds and those with biological relevance as carbohydrates, amino acids, peptides and nucleic acids.
A1 A4 A6 A9 A10 A14 A21
B3 B4
Contents
Topic
Sub-topic
Theme 1. Carboxylic acid derivatives
Clasification and general reactivity: addition-elimination. Esters. Amides. Acid halides and anhydrides. Nitriles.
Theme 2. Alpha Reactivity of Carboniyl Compounds
Enols and enolates: tautomerism, acidity, regioselectivity of enolate formation. Reactivity: halogenation, alkylation, aldol condensation, the Mannich reaction, the Stork reaction, the Claisen reaction, the Dieckmann reaction, the Reformatsky reaction.
Theme 3. Bifunctional Compounds
Diols and hydroxycarbonyl compounds. Dicarbonyl compounds. Alpha, beta-unsaturated carbonyl compounds.
Reactions of heterocycles. Ring-closing reactions. Aromatic heterocycles with five- and six-members: pyrrol, furane, thiophene and pyridine. Benzoderivatives: indole, quinoline and isoquinoline.
Theme 6. Carbohydrates and Nucleic Acids
Carbohydrates, clssification: monossacharides, oligosaccarhides and polisaccarhidess. Nucleosides and nucleotides. Polynucleotides and nucleic acids.
Theme 7. Amino Acids, Peptides and Proteins
Amino Acids: structure, propieties, reactivity and synthesis. Peptides: structure and synthesis. Proteins: structure and classification.
Planning
Methodologies / tests
Competencies
Ordinary class hours
Student’s personal work hours
Total hours
Introductory activities
A1
1
0
1
Guest lecture / keynote speech
A1 A4 A6 A9 A10 A25 B4 B3 C1 C8
30
60
90
Mixed objective/subjective test
A1 A4 A6 A10 A15 A21 B2 B3 B4 C1
4
4
8
Seminar
A1 A4 A6 A9 A10 A14 A15 A21 B2 B3 B4 C1 C8
12
36
48
Personalized attention
1
0
1
(*)The information in the planning table is for guidance only and does not take into account the heterogeneity of the students.
Methodologies
Methodologies
Description
Introductory activities
In the initial session teachers will be presented and the course will be described. The most important in relation to the content, planning, methodologies, assessment methods and literature aspects are discussed.
Guest lecture / keynote speech
30 theoretical sessions are scheduled in one group, in which the teacher will develop the fundamental contents of the program through theoretical explanations, type resolution problems and practical examples. The scripts of the content and / or develop presentations will be available on the website of the matter (moodle) prior to the development of lessons. With the help of these materials and other resources (bibliographic, internet ...) students will prepare lessons prior to your delivery way. Student participation will be encouraged through the development of questions or e-mails directed to the teacher before, during or after the lesson.
Mixed objective/subjective test
One final written examination is programmed final, which will objectively assess the degree of assimilation and the applicability of the contents of the subject by the student program. The objective test will include a single type of questions, which will be related to the structure, reactivity and synthesis of organic compounds, and that will determine whether the answers are correct.
Seminar
It will be conducted in 12 interactive small group sessions in which students will actively participate in the analysis and resolution of the problems posed by the teacher. Questionnaires solving exercises will be available on the website of the matter (moodle) prior to the development of the classes. Students will work on the analysis and resolution of problems prior to the delivery of seminar sessions.
Personalized attention
Methodologies
Seminar
Description
The students will have personalized attention in the schedule of tutorials for clarification of the key concepts of the subject exposed in large groups, the resolution of individual issues raised in the workshops and keynote sessions.
In addition, students can receive personalized information on any aspect of the matter during the hours of tutorials.
Assessment
Methodologies
Competencies
Description
Qualification
Seminar
A1 A4 A6 A9 A10 A14 A15 A21 B2 B3 B4 C1 C8
Attendance and active participation of students in the analysis and resolution of the problems posed by the teacher and asking questions during interactive sessions or before and after the development of the same by e-mail will be assessed.
25
Mixed objective/subjective test
A1 A4 A6 A10 A15 A21 B2 B3 B4 C1
Final written examination, where students must solve in limited time without support materials similar to those raised during seminar sessions and oral presentation problems.
70
Guest lecture / keynote speech
A1 A4 A6 A9 A10 A25 B4 B3 C1 C8
Attendance and active participation of the students by asking questions or by e-mail before or after the exhibition sessions were evaluated.
5
Assessment comments
<p>The assessment by the objective test (first or second chance) will contribute 70% of the final grade. In this regard,the score on the second occasion (July) replace the obtained at the first opportunity (February). Continuous evaluation (the work done in the master classes, seminars and oral presentations and by assessing writing solutions to problem sets) will contribute 30% of the final grade. The score on continuous assessment during the course may be stored on the second occasion (July).</p><p>To qualify PASS will be necessary (1) to reach 40% of the score of the objective tests and (2) to 50% of the overall score. Students who do not participate in activities that account for more than 25% of the final score will be graded as NOTFILED. Students who takemore than 25% of classroom activities and after presenting the evidence does not reach 40% of the points in the same or 50% of the overall score will receive the grade of FAIL. </p><p>According to the academic regulations, students are evaluated on the second occasion shall be eligible for Honorous Distinction if the maximum number of these was not completed in its entirety at the first opportunity. </p><p>According to the recommendation of the Commission on Quality of the Faculty of Science, the Honours students who achieve the highest marks in the first opportunities will be granted. The students tested on the second occasion shall be eligible for honors if the maximum number of licenses for the corresponding course has not been fully covered at the first opportunity.</p><p>Students with recognition of dedication and part-time and academic exemption of assistance, the professor may fully or partly exempt to attending the continuous evaluation
process. Students in this circumstance must pass a specific test that
leaves no doubt about achieving the powers of matter on two occasions.</p>
Solomons, T. G. W.; Fryhle, C. B. Organic Chemistry, 9th Ed.; Wiley, NJ, 2008. QO-131
Streitwieser A.; Heathcock, C., Introduction to Organic Chemistry, New Jersey, USA . Prentice Hall, 1998, QO-430
COVID-19's PLAN:
· Organic Chemistry : An Intermediate Text, Hoffman, Robert V. Second Edition. John Wiley and Sons. 2004. Acceso a través de la biblioteca Ebook Collection (EBSCOhost).
· Organic Chemistry, Fox, Marye Anne, Whitesell, James K. Ed. Jones and Bartlett Publishers, Inc (1787). 1997. Acceso a través de la biblioteca Ebook Collection (EBSCOhost).
· Química orgánica , Chemistry, Organic, Cabildo Miranda, Maria del Pilar, Ed. UNED. QD251. Acceso a través de la biblioteca, e-libro.
Davis, D. T., Aromatic HeterocyclicChemistry, Primers 2, Oxford 1992, QO-
Bailey, P. D., Organonitrogen Chemistry,Primers 38, Oxford 1996, QO-243
Recommendations
Subjects that it is recommended to have taken before
Organic Chemistry 1/610G01026
Organic Chemistry 2/610G01027
Subjects that are recommended to be taken simultaneously
Subjects that continue the syllabus
Experimental Organic Chemistry/610G01029
Advanced Organic Chemistry/610G01030
Other comments
(*)The teaching guide is the document in which the URV publishes the information about all its courses. It is a public document and cannot be modified. Only in exceptional cases can it be revised by the competent agent or duly revised so that it is in line with current legislation.