Laboratorio de Química 2 (LQ2) is an experimental curse and the attendance to all the evaluation activities is mandatory. For this reason, all the students will be graded in all activities with the flexibility that the coordination schedules and the material and human resources allow. To pass LQ2, it is necessary to obtain in the workshop, the mixed test, the practical text and the laboratory practices (corresponding to either the standard operations or the characterization of physicochemical properties) a note equal to or greater than 4 on 10. Therefore, students with a global grade equal to or greater than 5 who have not reached the qualification of 4 in any evaluable activity will be graded as not pass (grade of 4.5). Students who had not attended to the activities required to reach 25% of the global grade will receive the unpresented qualification. The students who have not reached the qualification of 4 in the advanced opportunity for the practical test will have to repeat it in the first or the second opportunity.

Regarding to the second opportunity of evaluation: (1) The qualifications of the laboratory practices (corresponding to either the standard operations or the characterization of physicochemical properties) will be preserved at the second opportunity. (2) The qualifications obtained for the practical test and mixed test in the second opportunity will substitute to those obtained in the the corresponding tests of the first opportunity. (3) The qualification obtained for the workshops could be preserved in the second opportunity or, in an alternative way, students could perform an optional exercise to evaluate the activities developed in the workshops during the course. (4) The students evaluated in the second opportunity will only be eligible for the Honored Grade (Matrícula de Honor) if the maximum number of these grades for the corresponding course has not been covered in full at the first opportunity.

The teaching-learning process, including the evaluation, refers to a complete academic course and, therefore, will start again with a new academic year, including all the activities and evaluation procedures that are schedulled for that course.

Students with part-time dedication will be evaluated with the criteria previously explained. Students with academic exemption from attendance or specific modalities of learning or support for diversity may be evaluated only through laboratory practices (standard operations and physical-chemical characterization), practical test and mixed test, both in the first as in the second opportunity (they will have dispensation of attendance to the workshops, corresponding to 10% of the global qualification). For those students who took advantage of the workshop attendance waiver, the mixed test will contribute to 40% of the overall score. The attendance to the laboratory practices is mandatory and the students will be graded with all the flexibility that the coordination schedules and the material and human resources available can offer. In the case of exceptional, objectivable and adequately justified circumstances, the responsible professor could exempt a student from attending the process of continuous evaluation of laboratory practices. The student who is in this circumstance must pass a specific examination (corresponding to 100% of the grade) precluding any doubt about the achievement of the knowledge, skills and competences of the subject.

Learning outcomes	Study programme competences
Perform standard laboratory operations for the preparation, separation and purification of organic compounds, materials handling safely, reagents and waste.	A1 A9 A12 A14 A15 A16 A17 A20 A21 A23 A26	B2 B3 B4	C1
Applying spectroscopic and spectrometric techniques in determining the structure of organic compounds.	A1 A9 A14 A15 A16 A21	B2 B3 B4	C1 C3
Application of electrochemical and spectroscopic techniques for the determination of the basic physicochemical properties of the compounds	A1 A7 A10 A17 A19 A23 A26	B2 B4	C1 C3
Being able to apply electrochemical and spectroscopic techniques for the determination of basic physicochemical properties of the compounds.	A14 A15 A20 A21	B2 B3	C1

Topic	Sub-topic
1. Standard laboratory operations.	Preparation, separation and purification of chemical compounds
2. Spectrometric techniques for determining molecular structure	Application of the 1H and 13C NMR, mass spectrometry, and infrared spectroscopy for structural determination. Characteristics frequency of the main functional groups. Tables of additivity.
3. Electrochemical and spectroscopic techniques for the physicochemical characterization of compounds.	Quantitative applications of electrochemical (potentiometry and conductimetry) and spectroscopic techniques : determination of reaction rates, equilibrium constants, molar masses, stoichiometry of the complexes, application of the Generalized Beer Law

Methodologies / tests	Competencies	Ordinary class hours	Student’s personal work hours	Total hours
Guest lecture / keynote speech	A1 A9 A21 B3	4	0	4
Seminar	A1 A9 A14 A15 A16 A21 B3 C1 C3	3	4.5	7.5
Workshop	A1 A9 A14 A15 A16 A21 B2 B3 B4 C1 C3	10	15	25
Laboratory practice	A1 A7 A10 A12 A14 A16 A17 A19 A20 A21 A23 A26 B3 B4 C1	39	65.5	104.5
Practical test:	A1 A7 A14 A15 A17 A19 A20 A21 A23 A26 B2 B3 B4	2	2	4
Mixed objective/subjective test	A1 A9 A14 A15 B2 B3	2	2	4

Personalized attention		1	0	1

(*)The information in the planning table is for guidance only and does not take into account the heterogeneity of the students.

Methodologies	Description
Guest lecture / keynote speech	In the first class a general presentation of the subject will be carried out: objective, contents and organization of the subject. In later sessions the basic notions of instrumentation, calibration and fundamentals of mass spectrometry will be explained.
Seminar	General aspects of the application of spectrometric and / or spectroscopic techniques in the structural determination.
Workshop	Resolution of practical cases of structural determination. The proposed problems will be solved, elaborating strategies that require the integration of data coming from the different spectroscopic techniques for the structural elucidation. Use of computer programs for the estimation of NMR data. Previously to some sessions, students must submitt (through Moodle) for some of the proposed problems.
Laboratory practice	The students will carry out the preparation, separation and structural determination of compounds (in the Standard Operations Laboratory) and will use electrochemical and spectroscopic techniques for the experimental determination of properties of compounds (in the Physicochemical Characterization Laboratory). In both Laboratories the students will develop the programmed experiences and should elaborate laboratory reports including the data obtained and their discussion, as well as the answers to the questions raised to deepen the understanding of the experiments carried out. The reports of the standard operations practices will be submitted through Moodle.
Practical test:	Realization of a practical test and resolution of questions in the laboratory, about the contents of the practices on characterization of physicochemical properties. Students will have an advanced opportunity to perform the practical test, once they have completed Physicochemical Characterization Laboratory.
Mixed objective/subjective test	The mixed test will include problems about structural elucidation from spectrometric and or spectroscopic data, analogous to those solved during the workshops

Methodologies	Competencies	Description	Qualification
Laboratory practice	A1 A7 A10 A12 A14 A16 A17 A19 A20 A21 A23 A26 B3 B4 C1	The organization, attitude and activity developed by the students during the laboratory sessions will be valued, as well as the corresponding laboratory reports, which must be submitted for evaluation.	40
Mixed objective/subjective test	A1 A9 A14 A15 B2 B3	The mixed test will consist of problems about structural determination, analogous to those solved in the workshops.	30
Practical test:	A1 A7 A14 A15 A17 A19 A20 A21 A23 A26 B2 B3 B4	A practical test with questions about the practices covering the characterization of physicochemical properties will be held in the laboratory. Students will have an advanced opportunity to perform the practical test, once they have completed the physicochemical characterization practices	20
Workshop	A1 A9 A14 A15 A16 A21 B2 B3 B4 C1 C3	The attitude and work carried out by the student during the problem solving sessions will be assessed. Solutions and reports submitted by the students will also be evaluated.	10

Assessment comments
Laboratorio de Química 2 (LQ2) is an experimental curse and the attendance to all the evaluation activities is mandatory. For this reason, all the students will be graded in all activities with the flexibility that the coordination schedules and the material and human resources allow. To pass LQ2, it is necessary to obtain in the workshop, the mixed test, the practical text and the laboratory practices (corresponding to either the standard operations or the characterization of physicochemical properties) a note equal to or greater than 4 on 10. Therefore, students with a global grade equal to or greater than 5 who have not reached the qualification of 4 in any evaluable activity will be graded as not pass (grade of 4.5). Students who had not attended to the activities required to reach 25% of the global grade will receive the unpresented qualification. The students who have not reached the qualification of 4 in the advanced opportunity for the practical test will have to repeat it in the first or the second opportunity. Regarding to the second opportunity of evaluation: (1) The qualifications of the laboratory practices (corresponding to either the standard operations or the characterization of physicochemical properties) will be preserved at the second opportunity. (2) The qualifications obtained for the practical test and mixed test in the second opportunity will substitute to those obtained in the the corresponding tests of the first opportunity. (3) The qualification obtained for the workshops could be preserved in the second opportunity or, in an alternative way, students could perform an optional exercise to evaluate the activities developed in the workshops during the course. (4) The students evaluated in the second opportunity will only be eligible for the Honored Grade (Matrícula de Honor) if the maximum number of these grades for the corresponding course has not been covered in full at the first opportunity. The teaching-learning process, including the evaluation, refers to a complete academic course and, therefore, will start again with a new academic year, including all the activities and evaluation procedures that are schedulled for that course. Students with part-time dedication will be evaluated with the criteria previously explained. Students with academic exemption from attendance or specific modalities of learning or support for diversity may be evaluated only through laboratory practices (standard operations and physical-chemical characterization), practical test and mixed test, both in the first as in the second opportunity (they will have dispensation of attendance to the workshops, corresponding to 10% of the global qualification). For those students who took advantage of the workshop attendance waiver, the mixed test will contribute to 40% of the overall score. The attendance to the laboratory practices is mandatory and the students will be graded with all the flexibility that the coordination schedules and the material and human resources available can offer. In the case of exceptional, objectivable and adequately justified circumstances, the responsible professor could exempt a student from attending the process of continuous evaluation of laboratory practices. The student who is in this circumstance must pass a specific examination (corresponding to 100% of the grade) precluding any doubt about the achievement of the knowledge, skills and competences of the subject.

Basic	José Ramón Pedro; Gonzalo Blay (2010). 200 Problemas de determinación estructural de compuestos orgánicos. Ed. Vision Libros, Madrid Skoog, D. A; Holler, F. James; Nieman, Timothy A. (2001). Análisis químico cuantitativo. Reverté Connors, K .A. ( 1987). Binding Constants. The Measurement of Molecular Complex Stability. Wiley & Sons: New York Espenson, J. H. (2002). Chemical Kinetics & Reaction Mechanisms.. 2ª ed, McGraw-Hill. Jonathan Clayden; Nick Greeves; Stuart Warren. (2012). Determining organic structures; 1H NMR: proton nuclear magnetic resonance. Capítulos 3 y 13 en: Organic Chemistry . 2nd Ed. Oxford University Press L. G. Wade, Jr. (2012). Espectroscopia de infrarroja y espectrometría de masas, Espectroscopia de resonancia magnética nuclear. Capítulos 12 y 13 en: Química Orgánica, volumen 1. 7ª Ed. Pearson K. Peter C. Vollhardt; Neil S. Schore (2008). Espectroscopia de resonancia magnética nuclear, Espectroscopia de infrarrojo y Espectrometría de masas. Capítulos 10 y 11 en: Química Orgánica, Estructura y Función. 5ª Ed. Ediciones Omega Levine, I. N. (2004). Fisicoquímica . 5ª ed., McGraw-Hill, Madrid. Andrade Garda, J. M.; Carlosena Zubieta, A.; Gómez Carracedo, M. P.; Maestro Saavedra, M. A.; Prieto (2017). Problems of instrumental analytical chemistry. A hands-on guide. World Scientific Castro, A. R.; Moreno Bondi, M. C.; Simonet Suau, B. M. (coords) (2012). Técnicas espectroscópicas en química analítica. Vol I: Aspectos básicos y espectrometría molecular. Síntesis Mª Ángeles Martínez Grau; Aurelio G Csákÿ. (2001). Técnicas experimentales en síntesis orgánica . Ed. Síntesis Gavira Vallejo, J. M.; Hernanz Gismero, A. (2007). Técnicas fisico-químicas en medio ambiente. UNED

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