Teaching GuideTerm Faculty of Science |
Mestrado Universitario en Investigación Química e Química Industrial (Plan 2017) |
Subjects |
Applied Coordination Chemistry |
Contents |
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Identifying Data | 2017/18 | |||||||||||||
Subject | Applied Coordination Chemistry | Code | 610509110 | |||||||||||
Study programme |
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Descriptors | Cycle | Period | Year | Type | Credits | |||||||||
Official Master's Degree | Yearly |
First | Optativa | 3 | ||||||||||
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Topic | Sub-topic |
Structural properties of coordination compounds. Characterization techniques | Structural properties in coordination compounds. Characterization techniques. - Spectroscopic techniques - Spectrometric techniques - Diffraction techniques - Techniques based on magnetic properties - Other techniques |
Activation of small molecules by coordination compounds | Structure and bonding in dioxygen and dinitrogen complexes: bonding modes. Synthesis of dioxygen and dinitrogen complexes. Structural characterization of dioxygen and dinitrogen complexes: NMR and IR spectroscopy, mass spectrometry, single crystal X-ray diffraction. Synthetic applications of dioxygen and dinitrogen complexes. Future perspectives. |
Coordination compounds with applications in medicine: therapeutic and diagnose tools | Coordination compounds with applications in medicine: therapeutic and diagnose tools - Antitumor metalodrugs. - Types of complexes according to the metal centre and the structure - Therapeutic mechanism. - Synthetic methods. Application of metal complexes as radiopharmaceuticals. - Properties and characteristics of the ligands and the radioisotope - Diagnostic, (PET, SPEC) and therapeutic techniques. Contrast agents in magnetic resonance imaging (MRI) Proton relaxation agents T1 (Gd3+, Mn2+ y Fe3+) y T2. Parameters affecting the efficiency. - Agents based on saturation transfer by chemical exchange (CEST). - Agents based on other nuclei (, 31P). - Hyperpolarization. |
Coordination compounds in the design of new materials: coordination polymers and MOFs. Properties and applications. | Types of systems arising from the metal-ligand association. Isolated and extensive associations (coordination polymers and MOFs) Main structural characteristics and characterization. Synthetic strategies and general characterization techniques. Properties and applications. |
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